Dioxygenyl

Dioxygenyl
Names
IUPAC name
Dioxygenyl
Identifiers
ChEBI
ChemSpider
  • InChI=1S/O2/c1-2/q+1
    Key: KMHJKRGRIJONSV-UHFFFAOYSA-N
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

The dioxygenyl ion, O+
2
, has been studied in both the gas phase and in salts with anions that cannot be oxidized. The first synthesis was O+
2
[PtF
6
]. Rather than the triple bond of O
2
, the bond order is considered to be 21/2. Relative to most molecules, this ionization energy is very high at 1175 kJ/mol. As a result, the scope of the chemistry of O+
2
is quite limited, acting mainly as a 1-electron oxidiser.